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Lupita Nyong'o - The 12 Years a Slave star continues her red carpet winning streak in this scorching hot Ralph Lauren cape gown. (Photo: Jason Merritt/Getty Images)

Photo By Photo: Jason Merritt/Getty Images

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Kerry Washington - Kerry is positively glowing in her custom Balenciaga gown with split-front detail, the perfect way to highlight her growing baby bump! (Photo: Jason Merritt/Getty Images)

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Zoe Saldana - Shine on! The Guardians of the Galaxy star accents her rhinestone-encrusted Prabal Gurung frock with classic nude pumps and scarlet lips.  (Photo: Jason Merritt/Getty Images)

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Usher - The singer-actor steps out in an eggplant-hued tux and snazzy bow tie, most definitely joining our list of sexy bow-tied stars.  (Photo: Jason Merritt/Getty Images)

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Angela Bassett - The American Horror Story star continues to defy time in her plunging Ines Di Santo gown, tousled waves and smoky eyes. (Photo: George Pimentel/WireImage)

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Rashida Jones - Rocking a crystal palm tree-embellished Fausto Puglisi gown, the actress brings her signature spunk to the scene. She finishes her look with a textured top knot and wine-stained lips. (Photo: Jason Merritt/Getty Images)

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Sofia Vergara - With its breathtaking silhouette, the Modern Family star brings the drama in her Zac Posen ball gown. We’re loving that turquoise necklace, too! (Photo: Jason Merritt/Getty Images)

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Diddy - The rapper-mogul proves you can’t go wrong in a crisp black tux, sexy bow tie and dark shades. (Photo: Jason Merritt/Getty Images)

Photo By Jason Merritt/Getty Images

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Camila Alves - The model goes for Old Hollywood glamour in a black sequin gown by Dolce & Gabbana and touchable waves. (Photo: George Pimentel/WireImage)

Photo By Photo: George Pimentel/WireImage

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Paula Patton - Paula flaunts her enviable curves in a cream Stéphane Rolland gown with stunning front ruffle, teaming it with gorgeous diamond drop earrings, matching wrist cuff and emerald statement ring. (Photo: Jason Merritt/Getty Images)

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Gabourey Sidibe - The American Horror Story star teams her shimmery Daniel Musto with Michael Costello gown with glamorous barrel curls and an embellished Deepa Gurnani clutch. (Photo: Jason Merritt/Getty Images)

Photo By Photo: Jason Merritt/Getty Images

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Chiwetel Ejiofor - Looking dapper in a classic suit and tie, the 12 Years a Slave star strikes a pose with girlfriend Sari Mercer. (Photo: Jason Merritt/Getty Images)

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Terry Crews - The Brooklyn Nine-Nine star mixes it up in a navy tux and funky, multi-color wingtips for added pizazz. (Photo: Trae Patton/NBC/NBC via Getty Images)

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Mike Tyson - We think Mike is a knockout in his black brocade-print suit jacket, crisp bow and patent oxfords. (Photo: Jason Merritt/Getty Images)

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Rocsi Diaz - The Entertainment Tonight correspondent is perfection in her textured J. Mendel gown, soft makeup and regal updo. (Photo: Jason Merritt/Getty Images)