Best Dressed of the Week: Keke Palmer's Velvet Crush

Plus, Jennifer Hudson, Cassie and more show-stopping looks.

Blue Velvet - Just call her Sexy Blue Velvet!  (Photo: Brad Barket/Getty Images for VH1)

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Keke Palmer - The actress' bold royal blue velvet jumpsuit by Fashion Nova, seen at the after-party for CrazySexyCool: The TLC Story, is yet another reason why she is one of our favorite style stars. And those silver ankle-strap heels are the business! (Photo: Brad Barket/Getty Images for VH1)

Photo By Photo: Brad Barket/Getty Images for VH1

Lupita Nyong'o - It’s all about the details for the actress, who catches our eye in this hot Miu Miu frock with bird-print design and pretty pleated skirt at the 12 Years a Slave premiere. And check out her scarlet T-strap pumps and coordinating clutch, which add lovely contrast to her sweet look.  (Photo: Kevin Winter/Getty Images)

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Lupita Nyong'o - It’s all about the details for the actress, who catches our eye in this hot Miu Miu frock with bird-print design and pretty pleated skirt at the 12 Years a Slave premiere. And check out her scarlet T-strap pumps and coordinating clutch, which add lovely contrast to her sweet look. (Photo: Kevin Winter/Getty Images)

High - Host Keshia Chante rocks some thigh-high boots and a sleek black outfit. (Photo:  Bennett Raglin/BET/Getty Images for BET)

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Keshia Chante - We love how our 106 & Park co-host chooses a black-on-black look, allowing her $420 made to order lace-up thigh-high boots by Tony Bianco to take center stage. (Photo by Bennett Raglin/BET/Getty Images for BET)

The Giver - Jennifer Hudson attends the 2013 Golden Heart Awards in celebration of God's Love We Deliver at Spring Studios in New York City. (Photo: Dimitrios Kambouris/Getty Images for Michael Kors)

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Jennifer Hudson - The songstress cranks up the heat in a black Michael Kors gown with lace inset and thigh-high slit at the God’s Love We Deliver 2013 Golden Heart Awards. Her soft lavender statement lips are an unexpected twist on the evening lip. (Photo: D imitrios Kambouris/Getty Images for Michael Kors)

Photo By Photo: D imitrios Kambouris/Getty Images for Michael Kors

 Kat Graham - If you haven’t already jumped on the printed suit bandwagon, let actress Kat Graham change your mind. The Swiss-born beauty mixes business with pleasure in a jacquard floral-print version by Juicy Couture at the GQ Men book launch.  (Photo: Lester Cohen/WireImage)

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 Kat Graham - If you haven’t already jumped on the printed suit bandwagon, let actress Kat Graham change your mind. The Swiss-born beauty mixes business with pleasure in a jacquard floral-print version by Juicy Couture at the GQ Men book launch. (Photo: Lester Cohen/WireImage)

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Jordin Sparks - We normally love Jordin’s bright and bubbly red carpet style, so we were surprised to see her go so sleek at the Aquafina FlavorSplash event. The singer works a short sleeved black turtleneck with leather leggings and classic peep toes.  (Photo: Imeh Akpanudosen/Getty Images for Aquafina FlavorSplash)

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Jordin Sparks - We normally love Jordin’s bright and bubbly red carpet style, so we were surprised to see her go so sleek at the Aquafina FlavorSplash event. The singer works a short sleeved black turtleneck with leather leggings and classic peep toes. (Photo: Imeh Akpanudosen/Getty Images for Aquafina FlavorSplash)

Michelle Williams  - The soulful singer rocks a dramatic Gucci dress with lace inset and seductive slit at the 2013 Skin Cancer Foundation Gala, topping off the look with long locks and strappy star-spangled stilettos.  (Photo: Laura Cavanaugh/Getty Images)

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Michelle Williams - The soulful singer rocks a dramatic Gucci dress with lace inset and seductive slit at the 2013 Skin Cancer Foundation Gala, topping off the look with long locks and strappy star-spangled stilettos. (Photo: Laura Cavanaugh/Getty Images)

Alicia Quarles - Breaking news: E! News correspondent Alicia Quarles is the latest celebrity to reaffirm that leather is here to stay for fall, donning an embellished Jewel by Lisa dress at the Elton John AIDS Foundation’s 12th Annual Enduring Vision Benefit.   (Photo: Dimitrios Kambouris/Getty Images)

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Alicia Quarles - Breaking news: E! News correspondent Alicia Quarles is the latest celebrity to reaffirm that leather is here to stay for fall, donning an embellished Jewel by Lisa dress at the Elton John AIDS Foundation’s 12th Annual Enduring Vision Benefit. (Photo: Dimitrios Kambouris/Getty Images)

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Cassie - Leave it to Cassie to make leather jogging pants sexy, and she definitely did so while grabbing dinner in Los Angeles (we’re already hunting for an identical version for ourselves). Her Iro leather sleeve jacket and classic black pumps are also on our wish list. (Photo: Devone Byrd, PacificCoastNews.com)

Sofia Vergara - The Modern Family star is always flaunting her best assets on the red carpet, but her ebony fit-and-flare frock at the We Are the Nobles premiere proves that she doesn’t have to show a ton of skin to get our attention.(Photo: JC Olivera/WireImage)

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Sofia Vergara - The Modern Family star is always flaunting her best assets on the red carpet, but her ebony fit-and-flare frock at the We Are the Nobles premiere proves that she doesn’t have to show a ton of skin to get our attention.(Photo: JC Olivera/WireImage)